THE BOOK OF SHADOWS - M
MALCOM (& JANE) - Episode 2.03
In the 1920s, a Witch called Nell tricked Malcolm, a powerful warlock, into a painting with a hidden spell that could only be seen by x-ray. Nell did this for revenge as Malcolm was having an affair with a warlock, Jane.
In the present, Jane took the painting to Prue, who though Jane wanted it auctioned at Buckland, but she actually wanted the Charmed Ones to free Malcolm, and had been searching for them for 70 years.
Prue helped free Malcolm, but she thought she was helping an innocent.

Powers
Malcolm has x-ray vision, which is how he saw the hidden spell. He can also blink from one place to another.

Janes powers are unknown.

Vanquish
Malcolm set fire to the painting after he had been rescued, and as he did this, Phoebe recited a spell to suck her, Malcolm and Jane into the painting. When they were inside, Phoebe recited another spell to get her and here sisters (who had been sucked into the painting) out of the painting, leaving Malcolm and Jane inside to burn.
MANTICORES - Episode 6.09
Vicious demons with forked tongues. They communicate with high pitched cries and tend to travel in packs.
Manticores mate with humans to create hybrids so they can blend in and hide in plain sight. They kill their mates after conception.

Powers
They have supernatural strength and venemous claws.
They can also shimmer from one place to another.

Vanquish
With a powerful potion made by Phoebe and Paige.
MATTHEW TATE - Episode 1.09
A Warlock from the past who tricked the Charmed Ones latest ancestory, Melinda Warren, into falling for him, only for him to steal her powers and have her burnt at the stake. Before she was burnt, however, she managed to strip his powers, claim the back and curse him into a locket.
The said locket was opened by Prue at Bucklands Auction House in the present (which was planted there by Prue's demon bosses, Rex Buckland and Hannah Webster, who wanted to destroy the Charmed Ones) and Matthew was released.
He wanted to destroy the line of Warren Witches, so he planned to steal the Charmed Ones Powers. He managed to copy Prue and Phoebe's powers, but not Piper's.

Powers
He has the gift to copy powers that are used against him. Once he's copied a power, they have no effect if used against him.

Vanquish
Matthew was cursed back into the locket by Melinda Warren (who had been ressurected to help the sisters). She used a potion that included a feather from a spotted owl, and this spell:

Outside of time, Outside of gain,
Know only sorrow, Know only pain.
MASSELIN - Episode 2.04
A demon who seeks willing, trusting souls and devours them to make himself stronger. The souls are trapped inside Masselin's body and the unfortunate ones are kept alive and tortured for the pleasure he gets from their suffering.
A band manager, Jeff Carlton, made a pact with Masselin, and promised that he would deliver the souls. In return, Carlton became more rich and powerful.
Carltons band, Dishwalla, played at P3, and the Charmed Ones were warned by Leo that Masselin was there.

Powers
Unknown.

Vanquish
He came into contact with some extra-strength antacid, whcih caused him to explode, freeing all his victims.
MORDAUNT - Episode 6.08
An evil sorcerer who made a pact with the Dark Knight to get Excalibur (the sword in the stone). However, once Piper had pulled the sword out of the stone, he realised he didn't need the Dark Knight, and decided to convince Piper that she was the true owner of the sword so she would be consumed by it's power.
He claimed to be a humble teacher in service of Excalibur and instructs the owner of the sword.
He got Phoebe and Paige out of the way by giving them ingredients for a vanquishing potion to kill the Dark Knight, but the ingredients he gave them had disasterous reults when mixed.
Once he had Piper consumed by the power of the sword, he killed all the knights of the round table and consumed their powers, making him strong enough to rule Excalibur.

Powers
He can conjure things out of thin air. he can also transport himself from place to place in a gulf of white smoke.

Vanquish
He was killed by Wyatt. Wyatt is the true owner of Excalibur, and Piper was just supposed to pass it on to him. So Wyatt used his telekinetic powers to drive the sword through Mordaunt, thus vanquishing him.
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